There’s some good stuff in this article, I think. https://www.yokogawa.com/ca/library/resources/white-papers/basics-of-orp/
Some of the really technical stuff I only skimmed. But I took some quotes/notes. If this is useful, cool. If not, I’ll delete, if it’s just clutter.
“ORP is measured in milivolts (mV), with no correction for solution temperature.”
“When measuring ORP an important feature to remember is that unlike pH, temperature compensation is not normally used for ORP measurements.”
“An ORP measuring electrode can either be a separate electrode (as seen in Figure 3.4a), a combination ORP/Reference electrode (as seen in Figure 3.4b), or a combination ORP/pH measuring electrode (as seen in Figure 3.4c). The choice depends on the application as well as customer installation requirements.”
"One drawback however, is that pH changes also affect the oxidizing potential of the available chlorine and the resultant ORP value.
Below a value of 1.9 pH, chlorine exists as a diatomic molecule (Cl2) in water. As the pH increases above 1.9, chlorine oxidizes water to produce HOCl and the ORP millivolt reading will go down. As the pH value continues to increase HOCl further dissociates into OCl- above a pH of 7.3."
"HOCl being more active that OCl- has a higher ORP value. So, as the pH increases, an ORP sensor detects a decrease in value which reflecting the decrease in HOCl. Therefore, if we were using ORP to monitor the diatomic Cl2 level, we would have a large mV reading to start with, but as it oxidizes with water reacting with the Calcium Thiosulfite to form a salt, the mV reading would decrease.
Since ORP varies with pH changes, as well as changes in the chlorine levels, we must compensate for the effects of any pH changes. This can be done by measuring the pH and ORP independent of one another and then calculating the effect of the pH change on the ORP using formulas and graphs. A simpler and more direct method is to compensate for the pH changes by replacing the standard Ag/AgCl reference electrode normally used with a pH measuring electrode. This is known as pH Compensated ORP (rH).
Since the pH measuring electrode output changes as the pH of the process changes it acts as a moving reference effectively cancelling out any change in pH and leaving only the mV value which is due to changes in diatomic chlorine (Cl2) levels."