I used polytherm from polysci but it became too viscous at lower temps (10c) and wouldnt pump through my Huber. It worked great at 190-200 but not so good cold so keep that in mind
Depending on how hardcore you want to get… Dowtherm T-66 is one of the most stable heat transfer fluids on the market and is rated for temps well in excess of anything we’d use in our industry.
I actually have used glycerin in my rotovap for years, it’s cheap and you can clean it with water; a rare blessing. I tried it in my hot condenser for my short path and it works, but the pump motor has a hard time until it heats up and loosens up (I have a Huber kiss which I can’t preheat the fluid before turning in the pump). It’s good in a closed system and you can probably push it to about 130-140, at 160 it will start dehydrating, though I’ve never pushed it that much. I don’t go any higher than 110/120 in my rotovap because it starts to evaporate (you can see glycerin vapor) and that’s all I need for a good purge. As long as it doesn’t dehydrate it lasts a long time too. I’ve had the same fluid in there for like a year or two.
I have also tried vegetable oil like @Roguelab suggests, I do not recommend this, even at 90-100c, the oil oxidizes quite readily and begins gumming up and charring even after like 10-20hrs of use. I still have the heater and it smells like rancid oil when I open the top despite switching to water and flushing like crazy.