Solvent polarity correlation.

I have been doing research into which solvents to use for chromatography and other post processes; also for my TLC test. I was wondering if there is a rule of thumb based on the polarity of the solvent that will help me choose the right solvent, or solvent mixture based on the polarity of the specific cannabinoid?

This is a good video to familiarize yourself with the different chromatographic methods.